Zero-strain reductive intercalation in a molecular framework

Reductive intercalation of potassium within the molecular framework Ag(3)[Fe(CN)(6)] gives rise to a volume strain that is an order of magnitude smaller than is typical for common ion-storage materials. We suggest that framework flexibility might be exploited as a general strategy for reducing cycli...

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Autores principales: Hill, Joshua A., Cairns, Andrew B., Lim, Jared J. K., Cassidy, Simon J., Clarke, Simon J., Goodwin, Andrew L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4396389/
https://www.ncbi.nlm.nih.gov/pubmed/25892969
http://dx.doi.org/10.1039/c4ce02364a
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author Hill, Joshua A.
Cairns, Andrew B.
Lim, Jared J. K.
Cassidy, Simon J.
Clarke, Simon J.
Goodwin, Andrew L.
author_facet Hill, Joshua A.
Cairns, Andrew B.
Lim, Jared J. K.
Cassidy, Simon J.
Clarke, Simon J.
Goodwin, Andrew L.
author_sort Hill, Joshua A.
collection PubMed
description Reductive intercalation of potassium within the molecular framework Ag(3)[Fe(CN)(6)] gives rise to a volume strain that is an order of magnitude smaller than is typical for common ion-storage materials. We suggest that framework flexibility might be exploited as a general strategy for reducing cycling strain in battery and ion-storage materials.
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spelling pubmed-43963892015-04-15 Zero-strain reductive intercalation in a molecular framework Hill, Joshua A. Cairns, Andrew B. Lim, Jared J. K. Cassidy, Simon J. Clarke, Simon J. Goodwin, Andrew L. CrystEngComm Chemistry Reductive intercalation of potassium within the molecular framework Ag(3)[Fe(CN)(6)] gives rise to a volume strain that is an order of magnitude smaller than is typical for common ion-storage materials. We suggest that framework flexibility might be exploited as a general strategy for reducing cycling strain in battery and ion-storage materials. Royal Society of Chemistry 2015-04-21 2015-01-16 /pmc/articles/PMC4396389/ /pubmed/25892969 http://dx.doi.org/10.1039/c4ce02364a Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Hill, Joshua A.
Cairns, Andrew B.
Lim, Jared J. K.
Cassidy, Simon J.
Clarke, Simon J.
Goodwin, Andrew L.
Zero-strain reductive intercalation in a molecular framework
title Zero-strain reductive intercalation in a molecular framework
title_full Zero-strain reductive intercalation in a molecular framework
title_fullStr Zero-strain reductive intercalation in a molecular framework
title_full_unstemmed Zero-strain reductive intercalation in a molecular framework
title_short Zero-strain reductive intercalation in a molecular framework
title_sort zero-strain reductive intercalation in a molecular framework
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4396389/
https://www.ncbi.nlm.nih.gov/pubmed/25892969
http://dx.doi.org/10.1039/c4ce02364a
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