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Thermodynamic Modeling of Poorly Complexing Metals in Concentrated Electrolyte Solutions: An X-Ray Absorption and UV-Vis Spectroscopic Study of Ni(II) in the NiCl(2)-MgCl(2)-H(2)O System

Knowledge of the structure and speciation of aqueous Ni(II)-chloride complexes is important for understanding Ni behavior in hydrometallurgical extraction. The effect of concentration on the first-shell structure of Ni(II) in aqueous NiCl(2) and NiCl(2)-MgCl(2) solutions was investigated by Ni K edg...

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Detalles Bibliográficos
Autores principales: Zhang, Ning, Brugger, Joël, Etschmann, Barbara, Ngothai, Yung, Zeng, Dewen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4401718/
https://www.ncbi.nlm.nih.gov/pubmed/25885410
http://dx.doi.org/10.1371/journal.pone.0119805