Synthesis of Anionic Phosphorus-Containing Heterocycles by Intramolecular Cyclizations Involving N-Functionalized Phosphinecarboxamides

We report that the 2-phosphaethynolate anion (PCO(−)) reacts with propargylamines in the presence of a proton source to afford novel N-derivatized phosphinecarboxamides bearing alkyne functionalities. Deprotonation of these species gives rise to novel five- and six-membered anionic heterocycles resu...

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Detalles Bibliográficos
Autores principales: Robinson, Thomas P, Goicoechea, Jose M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4405058/
https://www.ncbi.nlm.nih.gov/pubmed/25736217
http://dx.doi.org/10.1002/chem.201500628

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4405058/
https://www.ncbi.nlm.nih.gov/pubmed/25736217
http://dx.doi.org/10.1002/chem.201500628

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