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Synthesis of Anionic Phosphorus-Containing Heterocycles by Intramolecular Cyclizations Involving N-Functionalized Phosphinecarboxamides

We report that the 2-phosphaethynolate anion (PCO(−)) reacts with propargylamines in the presence of a proton source to afford novel N-derivatized phosphinecarboxamides bearing alkyne functionalities. Deprotonation of these species gives rise to novel five- and six-membered anionic heterocycles resu...

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Detalles Bibliográficos
Autores principales:	Robinson, Thomas P, Goicoechea, Jose M
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4405058/ https://www.ncbi.nlm.nih.gov/pubmed/25736217 http://dx.doi.org/10.1002/chem.201500628

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