Cargando…
Enantioselective Cross-Coupling of meso-Epoxides with Aryl Halides
[Image: see text] The first enantioselective cross-electrophile coupling of aryl bromides with meso-epoxides to form trans-β-arylcycloalkanols is presented. The reaction is catalyzed by a combination of (bpy)NiCl(2) and a chiral titanocene under reducing conditions. Yields range from 57 to 99% with...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2015
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4415026/ https://www.ncbi.nlm.nih.gov/pubmed/25716775 http://dx.doi.org/10.1021/jacs.5b01909 |