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Attempts to prepare an all-carbon indigoid system

First attempts are described to prepare a precursor for an all-carbon analog of indigo, the tetracyclic triene 4. Starting from indan-2-one (9) the α-methylene ketone 13 was prepared. Upon subjecting this compound to a McMurry coupling reaction, it dimerized to the bis-indene derivative 17, rather t...

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Detalles Bibliográficos
Autores principales: Yildizhan, Şeref, Hopf, Henning, Jones, Peter G
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419558/
https://www.ncbi.nlm.nih.gov/pubmed/25977710
http://dx.doi.org/10.3762/bjoc.11.42