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Crystal structures of (±)-(1SR,5SR,6SR,7SR,10SR,11SR,13RS,14SR)-13-hy­droxy-7-meth­oxy­meth­oxy-11,15,18,18-tetra­methyl-3-oxo-2,4-dioxa­tetra­cyclo­[12.3.1.0(1,5).0(6,11)]octa­dec-15-en-10-yl benzoate, its 13-epimer and 13-one derivative

The title compounds, C(29)H(38)O(8)·0.25C(5)H(12), (A), C(29)H(38)O(8), (B), and C(29)H(36)O(8), (C), are tetra­cyclic benzoates possessing a taxane skeleton with a fused dioxolane ring as the core structure. In the asymmetric unit of (A), there are two independent benzoate mol­ecules (A and A′) and...

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Detalles Bibliográficos
Autores principales: Oishi, Takeshi, Fukaya, Keisuke, Yamaguchi, Yu, Sugai, Tomoya, Watanabe, Ami, Sato, Takaaki, Chida, Noritaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420046/
https://www.ncbi.nlm.nih.gov/pubmed/25995857
http://dx.doi.org/10.1107/S2056989015006854