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Crystal structure of μ-peroxido-κ(4) O (1),O (2):O (1′),O (2′)-bis­[(nitrato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)dioxidouranium(VI)]

In the title dimeric complex, [{UO(2)(NO(3))(C(15)H(11)N(3))}(2)O(2)], a peroxide ion bridges the two uran­yl(VI) [O=U=O](2+) ions. The O—O bond length of the peroxide is 1.485 (6) Å and the mid-point of this bond is located at the inversion centre of the dimer. The U atom exhibits a distorted hexa­...

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Detalles Bibliográficos
Autores principales: Kawasaki, Takeshi, Kitazawa, Takafumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420076/
https://www.ncbi.nlm.nih.gov/pubmed/25995895
http://dx.doi.org/10.1107/S2056989015007987