Crystal structure of di-μ-chlorido-bis­[di­chlorido­bis­(methanol-κO)iridium(III)] dihydrate: a surprisingly simple chlorido­iridium(III) dinuclear complex with methanol ligands

The reaction between IrCl(3)·xH(2)O in methanol led to the formation of small amounts of the title compound, [Ir(2)Cl(6)(CH(3)OH)(4)]·2H(2)O, which consists of two IrCl(4)O(2) octa­hedra sharing an edge via chloride bridges. The mol­ecule lies across an inversion center. Each octa­hedron can be envi...

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Detalles Bibliográficos
Autores principales: Merola, Joseph S., Slebodnick, Carla, Houser, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420101/
https://www.ncbi.nlm.nih.gov/pubmed/25995872
http://dx.doi.org/10.1107/S2056989015006672

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420101/
https://www.ncbi.nlm.nih.gov/pubmed/25995872
http://dx.doi.org/10.1107/S2056989015006672

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