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Crystal structure of 3-(4-meth­oxy­phen­yl)-2,3-di­hydro-1H-naphtho­[2,1-b]pyran-1-one

In the title compound, C(20)H(16)O(3), the hydro­pyran ring adopts a distorted half-chair conformation with the methine C atom and the ring O atom displaced by −0.554 (2) and 0.158 (1) Å, respectively, from the plane of the other four atoms (r.m.s. deviation = 0.020 Å). Its mean plane (all atoms) is...

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Detalles Bibliográficos
Autores principales: Vasanthi, R., Reuben Jonathan, D., Elizhlarasi, K. S., Revathi, B. K., Usha, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420115/
https://www.ncbi.nlm.nih.gov/pubmed/25995933
http://dx.doi.org/10.1107/S2056989015007082
Descripción
Sumario:In the title compound, C(20)H(16)O(3), the hydro­pyran ring adopts a distorted half-chair conformation with the methine C atom and the ring O atom displaced by −0.554 (2) and 0.158 (1) Å, respectively, from the plane of the other four atoms (r.m.s. deviation = 0.020 Å). Its mean plane (all atoms) is inclined to the naphthalene ring system at a dihedral angle of 11.67 (1)°. The dihedral angle between the napthalene ring system and the phenyl ring is 71.84 (1)°. In the crystal, no diectional inter­actions beyond van der Waals contacts could be identified.