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Crystal structures of 1-(4-chlorophenyl)-2-(diphenylphosphoryl)ethan-1-one and 1-(diphenylphosphoryl)-3,3-dimethylbutan-2-one
The title compounds, C(20)H(16)ClO(2)P, (I), and C(18)H(21)O(2)P, (II), were synthesized via an Arbuzov reaction between an α-bromoketone and isopropoxydiphenylphosphane. In the crystals of both compounds, molecules are linked via bifurcated C—H⋯(O,O) hydrogen bonds, forming chains propagating a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420131/ https://www.ncbi.nlm.nih.gov/pubmed/25995871 http://dx.doi.org/10.1107/S2056989015006994 |