Crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one

The title compounds, C(20)H(16)ClO(2)P, (I), and C(18)H(21)O(2)P, (II), were synthesized via an Arbuzov reaction between an α-bromo­ketone and isopropoxydi­phenyl­phosphane. In the crystals of both compounds, mol­ecules are linked via bifurcated C—H⋯(O,O) hydrogen bonds, forming chains propagating a...

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Autores principales: Leach, Erin G., Kulesza, Alyssa A., Staples, Richard J., Biros, Shannon M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420131/
https://www.ncbi.nlm.nih.gov/pubmed/25995871
http://dx.doi.org/10.1107/S2056989015006994
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author Leach, Erin G.
Kulesza, Alyssa A.
Staples, Richard J.
Biros, Shannon M.
author_facet Leach, Erin G.
Kulesza, Alyssa A.
Staples, Richard J.
Biros, Shannon M.
author_sort Leach, Erin G.
collection PubMed
description The title compounds, C(20)H(16)ClO(2)P, (I), and C(18)H(21)O(2)P, (II), were synthesized via an Arbuzov reaction between an α-bromo­ketone and isopropoxydi­phenyl­phosphane. In the crystals of both compounds, mol­ecules are linked via bifurcated C—H⋯(O,O) hydrogen bonds, forming chains propagating along [100] for (I) and along [010] for (II). The chains are linked via C—H⋯π inter­actions, leading to the formation of sheets lying parallel to (010) for (I) and (001) for (II). The absolute structure of compound (II) was determined by resonant scattering [Flack parameter = 0.088 (14)].
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spelling pubmed-44201312015-05-20 Crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one Leach, Erin G. Kulesza, Alyssa A. Staples, Richard J. Biros, Shannon M. Acta Crystallogr E Crystallogr Commun Research Communications The title compounds, C(20)H(16)ClO(2)P, (I), and C(18)H(21)O(2)P, (II), were synthesized via an Arbuzov reaction between an α-bromo­ketone and isopropoxydi­phenyl­phosphane. In the crystals of both compounds, mol­ecules are linked via bifurcated C—H⋯(O,O) hydrogen bonds, forming chains propagating along [100] for (I) and along [010] for (II). The chains are linked via C—H⋯π inter­actions, leading to the formation of sheets lying parallel to (010) for (I) and (001) for (II). The absolute structure of compound (II) was determined by resonant scattering [Flack parameter = 0.088 (14)]. International Union of Crystallography 2015-04-22 /pmc/articles/PMC4420131/ /pubmed/25995871 http://dx.doi.org/10.1107/S2056989015006994 Text en © Leach et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Leach, Erin G.
Kulesza, Alyssa A.
Staples, Richard J.
Biros, Shannon M.
Crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one
title Crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one
title_full Crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one
title_fullStr Crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one
title_full_unstemmed Crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one
title_short Crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one
title_sort crystal structures of 1-(4-chloro­phen­yl)-2-(di­phenyl­phosphor­yl)ethan-1-one and 1-(di­phenyl­phosphor­yl)-3,3-di­methyl­butan-2-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420131/
https://www.ncbi.nlm.nih.gov/pubmed/25995871
http://dx.doi.org/10.1107/S2056989015006994
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