Sugar silanes: versatile reagents for stereocontrolled glycosylation via intramolecular aglycone delivery

A new method for the intramolecular glycosylation of alcohols is described. Utilizing carbohydrate-derived silanes, the catalytic dehydrogenative silylation of alcohols is followed by intramolecular glycosylation. Appropriate combinations of silane position and protecting groups allow highly selecti...

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Detalles Bibliográficos
Autores principales: Walk, Jordan T., Buchan, Zachary A., Montgomery, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4435934/
https://www.ncbi.nlm.nih.gov/pubmed/26000163
http://dx.doi.org/10.1039/c5sc00810g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4435934/
https://www.ncbi.nlm.nih.gov/pubmed/26000163
http://dx.doi.org/10.1039/c5sc00810g

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