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Sugar silanes: versatile reagents for stereocontrolled glycosylation via intramolecular aglycone delivery
A new method for the intramolecular glycosylation of alcohols is described. Utilizing carbohydrate-derived silanes, the catalytic dehydrogenative silylation of alcohols is followed by intramolecular glycosylation. Appropriate combinations of silane position and protecting groups allow highly selecti...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4435934/ https://www.ncbi.nlm.nih.gov/pubmed/26000163 http://dx.doi.org/10.1039/c5sc00810g |