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Crystal structure of tris­[μ(2)-bis­(di­phenyl­phosphan­yl)methane-κ(2) P:P′]di-μ(3)-bromido-tris­ilver(I) bromide–N,N′-phenyl­thio­urea (1/1)

The title complex, [Ag(3)Br(2)(C(25)H(22)P(2))(3)]Br·C(7)H(8)N(2)S, comprises a trinuclear [Ag(3)Br(2)(C(25)H(22)P(2))(3)](+) unit, a Br(−) anion and one N,N′-di­methyl­thio­urea mol­ecule (ptu). Three Ag(I) ions are linked via two μ(3)-bridging Br atoms, leading to a distorted triangular bipyramid...

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Detalles Bibliográficos
Autores principales: Nimthong-Roldán, Arunpatcha, Wattanakanjana, Yupa, Rodkeaw, Jintana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438794/
https://www.ncbi.nlm.nih.gov/pubmed/26029416
http://dx.doi.org/10.1107/S2056989015005150