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Serendipitous preparation of fac-(acetonitrile-κN)trichlorido[(1,2,5,6-η)-cycloocta-1,5-diene]iridium(III)
A reaction between [(COD)IrCl](2) (COD is cycloocta-1,5-diene), HCl and indene failed to provide the hoped for chloridoindenyliridium dimer, but instead produced the title compound, [IrCl(3)(CH(3)CN)(C(8)H(12))], which is an octahedral complex of iridium(III) with a chelating cycloocta-1,5-diene...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438853/ https://www.ncbi.nlm.nih.gov/pubmed/26029393 http://dx.doi.org/10.1107/S2056989015004855 |