Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III)

A reaction between [(COD)IrCl](2) (COD is cyclo­octa-1,5-diene), HCl and indene failed to provide the hoped for chlorido­indenyliridium dimer, but instead produced the title compound, [IrCl(3)(CH(3)CN)(C(8)H(12))], which is an octa­hedral complex of iridium(III) with a chelating cyclo­octa-1,5-diene...

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Detalles Bibliográficos
Autores principales: Morris, David M., Merola, Joseph S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438853/
https://www.ncbi.nlm.nih.gov/pubmed/26029393
http://dx.doi.org/10.1107/S2056989015004855
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author Morris, David M.
Merola, Joseph S.
author_facet Morris, David M.
Merola, Joseph S.
author_sort Morris, David M.
collection PubMed
description A reaction between [(COD)IrCl](2) (COD is cyclo­octa-1,5-diene), HCl and indene failed to provide the hoped for chlorido­indenyliridium dimer, but instead produced the title compound, [IrCl(3)(CH(3)CN)(C(8)H(12))], which is an octa­hedral complex of iridium(III) with a chelating cyclo­octa-1,5-diene ligand, three chloride ligands in a fac arrangement, and one aceto­nitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful.
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spelling pubmed-44388532015-05-30 Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III) Morris, David M. Merola, Joseph S. Acta Crystallogr E Crystallogr Commun Research Communications A reaction between [(COD)IrCl](2) (COD is cyclo­octa-1,5-diene), HCl and indene failed to provide the hoped for chlorido­indenyliridium dimer, but instead produced the title compound, [IrCl(3)(CH(3)CN)(C(8)H(12))], which is an octa­hedral complex of iridium(III) with a chelating cyclo­octa-1,5-diene ligand, three chloride ligands in a fac arrangement, and one aceto­nitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful. International Union of Crystallography 2015-03-14 /pmc/articles/PMC4438853/ /pubmed/26029393 http://dx.doi.org/10.1107/S2056989015004855 Text en © Morris and Merola 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Morris, David M.
Merola, Joseph S.
Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III)
title Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III)
title_full Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III)
title_fullStr Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III)
title_full_unstemmed Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III)
title_short Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III)
title_sort serendipitous preparation of fac-(aceto­nitrile-κn)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(iii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438853/
https://www.ncbi.nlm.nih.gov/pubmed/26029393
http://dx.doi.org/10.1107/S2056989015004855
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