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Effect of Au nano-particle aggregation on the deactivation of the AuCl(3)/AC catalyst for acetylene hydrochlorination

A detailed study of the valence state and distribution of the AuCl(3)/AC catalyst during the acetylene hydrochlorination deactivation process is described and discussed. Temperature-programmed reduction and X-ray photoelectron spectral analysis indicate that the active Au(3+) reduction to metallic A...

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Detalles Bibliográficos
Autores principales: Dai, Bin, Wang, Qinqin, Yu, Feng, Zhu, Mingyuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4440204/
https://www.ncbi.nlm.nih.gov/pubmed/25994222
http://dx.doi.org/10.1038/srep10553