Mechanistic Significance of the Si–O–Pd Bond in the Palladium-Catalyzed Cross-Coupling Reactions of Alkenylsilanolates

[Image: see text] Through the combination of reaction kinetics (both catalytic and stoichiometric) and solid-state characterization of arylpalladium(II) alkenylsilanolate complexes, the intermediacy of covalent adducts containing Si–O–Pd linkages in the cross-coupling reactions of organosilanolates...

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Detalles Bibliográficos
Autores principales: Tymonko, Steven A., Smith, Russell C., Ambrosi, Andrea, Denmark, Scott E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4442670/
https://www.ncbi.nlm.nih.gov/pubmed/25945390
http://dx.doi.org/10.1021/jacs.5b02515

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4442670/
https://www.ncbi.nlm.nih.gov/pubmed/25945390
http://dx.doi.org/10.1021/jacs.5b02515

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