Alternative Synthesis and Structures of C-monoacetylenic Phosphaalkenes

An alternative synthesis of C-monoacetylenic phosphaalkenes trans-Mes*P=C(Me)(C≡CR) (Mes* = 2, 4, 6-(t)Bu(3)Ph, R = Ph, SiMe(3)) from C-bromophosphaalkenes cis-Mes*P=C(Me)Br using standard Sonogashira coupling conditions is described. Crystallographic studies confirm cis-trans isomerization of the P...

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Detalles Bibliográficos
Autores principales: Orthaber, Andreas, Öberg, Elisabet, Jane, Reuben T, Ott, Sascha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2012
Materias:
Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4456767/
https://www.ncbi.nlm.nih.gov/pubmed/26063932
http://dx.doi.org/10.1002/zaac.201200324

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4456767/
https://www.ncbi.nlm.nih.gov/pubmed/26063932
http://dx.doi.org/10.1002/zaac.201200324

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