Crystal structure of μ-cyanido-1:2κ(2) N:C-dicyanido-1κC,2κC-bis­(quinolin-8-amine-1κ(2) N,N′)-2-silver(I)-1-silver(II): rare occurrence of a mixed-valence Ag(I,II) compound

The title dinuclear complex, [Ag(2)(CN)(3)(C(9)H(8)N(2))(2)], may be considered as an Ag(II) compound with the corresponding metal site coordinated by two bidentate quinolin-8-amine mol­ecules, one cyanide group and one dicyanidoargentate(I) anion, [Ag(CN)(2)](−). Since this latter ligand contains a...

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Detalles Bibliográficos
Autores principales: Setifi, Zouaoui, Bernès, Sylvain, Pérez, Olivier, Setifi, Fatima, Rouag, Djamil-Azzeddine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459308/
https://www.ncbi.nlm.nih.gov/pubmed/26090154
http://dx.doi.org/10.1107/S2056989015009664

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4459308/
https://www.ncbi.nlm.nih.gov/pubmed/26090154
http://dx.doi.org/10.1107/S2056989015009664

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