Multivalent polyglycerol supported imidazolidin-4-one organocatalysts for enantioselective Friedel–Crafts alkylations

The first immobilization of a MacMillan’s first generation organocatalyst onto dendritic support is described. A modified tyrosine-based imidazolidin-4-one was grafted to a soluble high-loading hyperbranched polyglycerol via a copper-catalyzed alkyne–azide cycloaddition (CuAAC) reaction and readily...

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Detalles Bibliográficos
Autores principales: Pecchioli, Tommaso, Muthyala, Manoj Kumar, Haag, Rainer, Christmann, Mathias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4463494/
https://www.ncbi.nlm.nih.gov/pubmed/26150897
http://dx.doi.org/10.3762/bjoc.11.83

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4463494/
https://www.ncbi.nlm.nih.gov/pubmed/26150897
http://dx.doi.org/10.3762/bjoc.11.83

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