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Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles

Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO(4) or, alternatively, under high-pressure conditions (5 kbar) at room temperature yielding thiopyran derivatives. The hetero-Diels–Alder reaction occurs in a chemo- and regioselec...

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Detalles Bibliográficos
Autores principales: Mlostoń, Grzegorz, Grzelak, Paulina, Mikina, Maciej, Linden, Anthony, Heimgartner, Heinz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464410/
https://www.ncbi.nlm.nih.gov/pubmed/26124858
http://dx.doi.org/10.3762/bjoc.11.63