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Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles

Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO(4) or, alternatively, under high-pressure conditions (5 kbar) at room temperature yielding thiopyran derivatives. The hetero-Diels–Alder reaction occurs in a chemo- and regioselec...

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Detalles Bibliográficos
Autores principales:	Mlostoń, Grzegorz, Grzelak, Paulina, Mikina, Maciej, Linden, Anthony, Heimgartner, Heinz
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2015
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464410/ https://www.ncbi.nlm.nih.gov/pubmed/26124858 http://dx.doi.org/10.3762/bjoc.11.63

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