Weakly nucleophilic potassium aryltrifluoroborates in palladium-catalyzed Suzuki–Miyaura reactions: relative reactivity of K[4-RC(6)F(4)BF(3)] and the role of silver-assistance in acceleration of transmetallation

Small differences in the reactivity of weakly nucleophilic potassium aryltrifluoroborates are revealed in the silver-assisted Pd-catalyzed cross-coupling of K[4-RC(6)F(4)BF(3)] (R = H, Bu, MeO, EtO, PrO, iPrO, BuO, t-BuO, CH(2)=CHCH(2)O, PhCH(2)O, PhCH(2)CH(2)O, PhO, F, pyrazol-1-yl, pyrrol-1-yl, an...

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Detalles Bibliográficos
Autores principales: Bardin, Vadim V, Shabalin, Anton Yu, Adonin, Nicolay Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464464/
https://www.ncbi.nlm.nih.gov/pubmed/26124862
http://dx.doi.org/10.3762/bjoc.11.68

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464464/
https://www.ncbi.nlm.nih.gov/pubmed/26124862
http://dx.doi.org/10.3762/bjoc.11.68

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