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Weakly nucleophilic potassium aryltrifluoroborates in palladium-catalyzed Suzuki–Miyaura reactions: relative reactivity of K[4-RC(6)F(4)BF(3)] and the role of silver-assistance in acceleration of transmetallation
Small differences in the reactivity of weakly nucleophilic potassium aryltrifluoroborates are revealed in the silver-assisted Pd-catalyzed cross-coupling of K[4-RC(6)F(4)BF(3)] (R = H, Bu, MeO, EtO, PrO, iPrO, BuO, t-BuO, CH(2)=CHCH(2)O, PhCH(2)O, PhCH(2)CH(2)O, PhO, F, pyrazol-1-yl, pyrrol-1-yl, an...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464464/ https://www.ncbi.nlm.nih.gov/pubmed/26124862 http://dx.doi.org/10.3762/bjoc.11.68 |