Catalytic 1,4-Rhodium(III) Migration Enables 1,3-Enynes to Function as One-Carbon Oxidative Annulation Partners in C–H Functionalizations**

1,3-Enynes containing allylic hydrogens cis to the alkyne are shown to act as one-carbon partners, rather than two-carbon partners, in various rhodium-catalyzed oxidative annulations. The mechanism of these unexpected transformations is proposed to occur through double C–H activation, involving a hi...

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Detalles Bibliográficos
Autores principales: Burns, David J, Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464529/
https://www.ncbi.nlm.nih.gov/pubmed/25048465
http://dx.doi.org/10.1002/anie.201406072

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464529/
https://www.ncbi.nlm.nih.gov/pubmed/25048465
http://dx.doi.org/10.1002/anie.201406072

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