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Iridium-Catalyzed Arylative Cyclization of Alkynones by 1,4-Iridium Migration**
1,4-Metal migrations enable the remote functionalization of C—H bonds, and have been utilized in a wide variety of valuable synthetic methods. The vast majority of existing examples involve the 1,4-migration of palladium or rhodium. Herein, the stereoselective synthesis of complex polycycles by the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464530/ https://www.ncbi.nlm.nih.gov/pubmed/24842318 http://dx.doi.org/10.1002/anie.201403271 |