The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide–Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex**

The ketimide anion R(2)C—N(−) is an important class of chemically robust ligand that binds strongly to metal ions and is considered ideal for supporting reactive metal fragments due to its inert spectator nature; this contrasts with R(2)N(−) amides that exhibit a wide range of reactivities. Here, we...

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Detalles Bibliográficos
Autores principales: Lu, Erli, Lewis, William, Blake, Alexander J, Liddle, Stephen T
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464536/
https://www.ncbi.nlm.nih.gov/pubmed/25044515
http://dx.doi.org/10.1002/anie.201404898

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464536/
https://www.ncbi.nlm.nih.gov/pubmed/25044515
http://dx.doi.org/10.1002/anie.201404898

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