Generation and Trapping of Ketenes in Flow

Ketenes were generated by the thermolysis of alkoxyalkynes under flow conditions, and then trapped with amines and alcohols to cleanly give amides and esters. For a 10 min reaction time, temperatures of 180, 160, and 140 °C were required for >95 % conversion of EtO, iPrO, and tBuO alkoxyalkynes,...

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Detalles Bibliográficos
Autores principales: Henry, Cyril, Bolien, David, Ibanescu, Bogdan, Bloodworth, Sally, Harrowven, David C, Zhang, Xunli, Craven, Andy, Sneddon, Helen F, Whitby, Richard J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464552/
https://www.ncbi.nlm.nih.gov/pubmed/26097406
http://dx.doi.org/10.1002/ejoc.201403603

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464552/
https://www.ncbi.nlm.nih.gov/pubmed/26097406
http://dx.doi.org/10.1002/ejoc.201403603

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