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Improving the Photocatalytic Reduction of CO(2) to CO through Immobilisation of a Molecular Re Catalyst on TiO(2)

The photocatalytic activity of phosphonated Re complexes, [Re(2,2′-bipyridine-4,4′-bisphosphonic acid) (CO)(3)(L)] (ReP; L=3-picoline or bromide) immobilised on TiO(2) nanoparticles is reported. The heterogenised Re catalyst on the semiconductor, ReP–TiO(2) hybrid, displays an improvement in CO(2) r...

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Detalles Bibliográficos
Autores principales: Windle, Christopher D, Pastor, Ernest, Reynal, Anna, Whitwood, Adrian C, Vaynzof, Yana, Durrant, James R, Perutz, Robin N, Reisner, Erwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4471553/
https://www.ncbi.nlm.nih.gov/pubmed/25639778
http://dx.doi.org/10.1002/chem.201405041