Direct Synthesis of 5-Aryl Barbituric Acids by Rhodium(II)-Catalyzed Reactions of Arenes with Diazo Compounds**

A commercially available rhodium(II) complex catalyzes the direct arylation of 5-diazobarbituric acids with arenes, allowing straightforward access to 5-aryl barbituric acids. Free N—H groups are tolerated on the barbituric acid, with no complications arising from N—H insertion processes. This metho...

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Detalles Bibliográficos
Autores principales: Best, Daniel, Burns, David J, Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4479025/
https://www.ncbi.nlm.nih.gov/pubmed/25959544
http://dx.doi.org/10.1002/anie.201502324

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4479025/
https://www.ncbi.nlm.nih.gov/pubmed/25959544
http://dx.doi.org/10.1002/anie.201502324

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