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Promoting C–C Bond Coupling of Benzyne and Methyl Ligands in Electron-Deficient (triphos)Pt–CH(3)(+) Complexes
[Image: see text] In situ generated benzyne reacts at room temperature with (triphos)Pt–CH(3)(+) to form a five-coordinate π-complex (2) that is isolable and stable in solution. Thermolysis of 2 at 60 °C generates (triphos)Pt(o-tolyl)(+) (3), which is the product of formal migratory insertion of CH(...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4480611/ https://www.ncbi.nlm.nih.gov/pubmed/26146438 http://dx.doi.org/10.1021/acs.organomet.5b00121 |