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Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes

[Image: see text] The chemistry of Au(I) complexes with two types of cyclic (alkyl)(amino)carbene (CAAC) ligands has been explored, using the sterically less demanding dimethyl derivative (Me2)CAAC and the 2-adamantyl ligand (Ad)CAAC. The conversion of ((Ad)CAAC)AuCl into ((Ad)CAAC)AuOH by treatment...

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Detalles Bibliográficos
Autores principales: Romanov, Alexander S., Bochmann, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4482412/
https://www.ncbi.nlm.nih.gov/pubmed/26146436
http://dx.doi.org/10.1021/om501211p