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Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)
[Image: see text] Two unique organometallic halide series (Ph(3)P)Au(4-Me-C(6)H(4))(CF(3))(X) and (Cy(3)P)Au(4-F-C(6)H(4))(CF(3))(X) (X = I, Br, Cl, F) have been synthesized. The PPh(3)-supported complexes can undergo both C(aryl)–X and C(aryl)–CF(3) reductive elimination. Mechanistic studies of the...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4482415/ https://www.ncbi.nlm.nih.gov/pubmed/26065722 http://dx.doi.org/10.1021/jacs.5b04613 |