Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid

Triflic acid (HOTf)-bound nonheme Mn(iv)-oxo complexes, [(L)Mn(IV)(O)](2+)–(HOTf)(2) (L = N4Py and Bn-TPEN; N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine and Bn-TPEN = N-benzyl-N,N′,N′-tris(2-pyridylmethyl)ethane-1,2-diamine), were synthesized by adding HOTf to the solutions of the [(L...

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Detalles Bibliográficos
Autores principales: Chen, Junying, Yoon, Heejung, Lee, Yong-Min, Seo, Mi Sook, Sarangi, Ritimukta, Fukuzumi, Shunichi, Nam, Wonwoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4486364/
https://www.ncbi.nlm.nih.gov/pubmed/26146538
http://dx.doi.org/10.1039/c5sc00535c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4486364/
https://www.ncbi.nlm.nih.gov/pubmed/26146538
http://dx.doi.org/10.1039/c5sc00535c

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