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Synthesis and Antifeedant Activity of Racemic and Optically Active Hydroxy Lactones with the p-Menthane System

Two racemic and two enantiomeric pairs of new δ-hydroxy-γ-lactones based on the p-menthane system were prepared from racemic and optically active cis- and trans-piperitols. The Johnson-Claisen rearrangement of the piperitols, epoxidation of the γδ-unsaturated esters, and acidic lactonization of the...

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Detalles Bibliográficos
Autores principales: Grudniewska, Aleksandra, Kłobucki, Marek, Dancewicz, Katarzyna, Szczepanik, Maryla, Gabryś, Beata, Wawrzeńczyk, Czesław
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4488555/
https://www.ncbi.nlm.nih.gov/pubmed/26132506
http://dx.doi.org/10.1371/journal.pone.0131028