Asymmetric hydrosilylation of ketones catalyzed by complexes formed from trans-diaminocyclohexane-based diamines and diethylzinc

ABSTRACT: Chiral acyclic and macrocyclic amines derived from trans-1,2-diaminocyclohexane in complexes with diethylzinc efficiently catalyze asymmetric hydrosilylation of aryl–alkyl and aryl–aryl ketones with enantiomeric excess of the product up to 86 %. A trianglamine ligand with a cyclic structur...

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Detalles Bibliográficos
Autores principales: Gajewy, Jadwiga, Gawronski, Jacek, Kwit, Marcin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2012
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4494764/
https://www.ncbi.nlm.nih.gov/pubmed/26166868
http://dx.doi.org/10.1007/s00706-012-0754-0

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4494764/
https://www.ncbi.nlm.nih.gov/pubmed/26166868
http://dx.doi.org/10.1007/s00706-012-0754-0

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