Electronic and solvent effects on kinetics of S(N)Ar substitution reactions of substituted anilines with 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole in MeOH–Me(2)SO mixtures of varying composition: one reaction with two mechanistic pathways

ABSTRACT: The kinetics and mechanism of the aromatic nucleophilic substitution reactions of 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole with para-X-substituted anilines (X = OH, OMe, Me, H, F, I, Cl) were studied in MeOH–Me(2)SO mixtures and pure Me(2)SO at 25.0 °C. The second-order rate coeffi...

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Detalles Bibliográficos
Autores principales: El Guesmi, Nizar, Berionni, Guillaume, Asghar, Basim H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2013
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4495024/
https://www.ncbi.nlm.nih.gov/pubmed/26166874
http://dx.doi.org/10.1007/s00706-013-1030-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4495024/
https://www.ncbi.nlm.nih.gov/pubmed/26166874
http://dx.doi.org/10.1007/s00706-013-1030-7

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