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Experimental and computational study on the reactivity of 2,3-bis[(3-pyridylmethyl)amino]-2(Z)-butene-1,4-dinitrile, a key intermediate for the synthesis of tribenzoporphyrazine bearing peripheral methyl(3-pyridylmethyl)amino substituents

ABSTRACT: An earlier developed alkylating path leading to tetraalkylated diaminomaleonitrile derivatives was explored. Attempts to explain the reactivity of the representative dialkylated diaminomaleonitrile 2,3-bis[(3-pyridylmethyl)amino]-2(Z)-butene-1,4-dinitrile during the alkylation reaction wer...

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Detalles Bibliográficos
Autores principales: Goslinski, Tomasz, Dutkiewicz, Zbigniew, Kryjewski, Michal, Tykarska, Ewa, Sobotta, Lukasz, Szczolko, Wojciech, Gdaniec, Maria, Mielcarek, Jadwiga
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4495027/
https://www.ncbi.nlm.nih.gov/pubmed/26166858
http://dx.doi.org/10.1007/s00706-011-0503-9