On the Role of Pre- and Post-Electron-Transfer Steps in the SmI(2)/Amine/H(2)O-Mediated Reduction of Esters: New Mechanistic Insights and Kinetic Studies

The mechanism of the SmI(2)-mediated reduction of unactivated esters has been studied using a combination of kinetic, radical clocks and reactivity experiments. The kinetic data indicate that all reaction components (SmI(2), amine, H(2)O) are involved in the rate equation and that electron transfer...

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Detalles Bibliográficos
Autores principales: Szostak, Michal, Spain, Malcolm, Procter, David J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497321/
https://www.ncbi.nlm.nih.gov/pubmed/24615806
http://dx.doi.org/10.1002/chem.201400295

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497321/
https://www.ncbi.nlm.nih.gov/pubmed/24615806
http://dx.doi.org/10.1002/chem.201400295

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