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On the Role of Pre- and Post-Electron-Transfer Steps in the SmI(2)/Amine/H(2)O-Mediated Reduction of Esters: New Mechanistic Insights and Kinetic Studies
The mechanism of the SmI(2)-mediated reduction of unactivated esters has been studied using a combination of kinetic, radical clocks and reactivity experiments. The kinetic data indicate that all reaction components (SmI(2), amine, H(2)O) are involved in the rate equation and that electron transfer...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
WILEY-VCH Verlag
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497321/ https://www.ncbi.nlm.nih.gov/pubmed/24615806 http://dx.doi.org/10.1002/chem.201400295 |