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Covalent Embedding of Ni(2+)/Fe(3+) Cyanometallate Structures in Silica by Sol–Gel Processing

Compound [Ni(AEAPTS)(2)](3)[Fe(CN)(6)](2) (AEAPTS=N-(2-aminoethyl)-3-aminopropyltrimethoxysilane), in which Ni(2+) and Fe(3+) ions are ferromagnetically coupled through cyano bridges, was prepared. Sol–gel processing of the AEAPTS derivative resulted in incorporation of the cyanometallate in silica....

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Detalles Bibliográficos
Autores principales: Felbermair, Elisabeth, Sidorenko, Andrey, Paschen, Silke, Akbarzadeh, Johanna, Peterlik, Herwig, Schubert, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497326/
https://www.ncbi.nlm.nih.gov/pubmed/24867432
http://dx.doi.org/10.1002/chem.201402805