Experimental and Computational Evidence for the Mechanism of Intradiol Catechol Dioxygenation by Non-Heme Iron(III) Complexes

Catechol intradiol dioxygenation is a unique reaction catalyzed by iron-dependent enzymes and non-heme iron(III) complexes. The mechanism by which these systems activate dioxygen in this important metabolic process remains controversial. Using a combination of kinetic measurements and computational...

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Detalles Bibliográficos
Autores principales: Jastrzebski, Robin, Quesne, Matthew G, Weckhuysen, Bert M, de Visser, Sam P, Bruijnincx, Pieter C A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497327/
https://www.ncbi.nlm.nih.gov/pubmed/25322920
http://dx.doi.org/10.1002/chem.201404988

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497327/
https://www.ncbi.nlm.nih.gov/pubmed/25322920
http://dx.doi.org/10.1002/chem.201404988

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