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Experimental and Computational Evidence for the Mechanism of Intradiol Catechol Dioxygenation by Non-Heme Iron(III) Complexes

Catechol intradiol dioxygenation is a unique reaction catalyzed by iron-dependent enzymes and non-heme iron(III) complexes. The mechanism by which these systems activate dioxygen in this important metabolic process remains controversial. Using a combination of kinetic measurements and computational...

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Detalles Bibliográficos
Autores principales:	Jastrzebski, Robin, Quesne, Matthew G, Weckhuysen, Bert M, de Visser, Sam P, Bruijnincx, Pieter C A
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2014
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497327/ https://www.ncbi.nlm.nih.gov/pubmed/25322920 http://dx.doi.org/10.1002/chem.201404988

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