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[FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**
The synthesis and crystallographic characterization of a complex possessing a well-defined {2Fe3S(μ-H)} core gives access to a paramagnetic bridging hydride with retention of the core geometry. Chemistry of this 35-electron species within the confines of a thin-layer FTIR spectro-electrochemistry ce...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497599/ https://www.ncbi.nlm.nih.gov/pubmed/25079249 http://dx.doi.org/10.1002/anie.201406210 |