[FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**

The synthesis and crystallographic characterization of a complex possessing a well-defined {2Fe3S(μ-H)} core gives access to a paramagnetic bridging hydride with retention of the core geometry. Chemistry of this 35-electron species within the confines of a thin-layer FTIR spectro-electrochemistry ce...

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Detalles Bibliográficos
Autores principales: Jablonskytė, Aušra, Wright, Joseph A, Fairhurst, Shirley A, Webster, Lee R, Pickett, Christopher J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497599/
https://www.ncbi.nlm.nih.gov/pubmed/25079249
http://dx.doi.org/10.1002/anie.201406210
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author Jablonskytė, Aušra
Wright, Joseph A
Fairhurst, Shirley A
Webster, Lee R
Pickett, Christopher J
author_facet Jablonskytė, Aušra
Wright, Joseph A
Fairhurst, Shirley A
Webster, Lee R
Pickett, Christopher J
author_sort Jablonskytė, Aušra
collection PubMed
description The synthesis and crystallographic characterization of a complex possessing a well-defined {2Fe3S(μ-H)} core gives access to a paramagnetic bridging hydride with retention of the core geometry. Chemistry of this 35-electron species within the confines of a thin-layer FTIR spectro-electrochemistry cell provides evidence for a unprecedented super-reduced Fe(I)(μ-H)Fe(I) intermediate.
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spelling pubmed-44975992015-07-10 [FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States** Jablonskytė, Aušra Wright, Joseph A Fairhurst, Shirley A Webster, Lee R Pickett, Christopher J Angew Chem Int Ed Engl Communications The synthesis and crystallographic characterization of a complex possessing a well-defined {2Fe3S(μ-H)} core gives access to a paramagnetic bridging hydride with retention of the core geometry. Chemistry of this 35-electron species within the confines of a thin-layer FTIR spectro-electrochemistry cell provides evidence for a unprecedented super-reduced Fe(I)(μ-H)Fe(I) intermediate. WILEY-VCH Verlag 2014-09-15 2014-07-30 /pmc/articles/PMC4497599/ /pubmed/25079249 http://dx.doi.org/10.1002/anie.201406210 Text en © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Jablonskytė, Aušra
Wright, Joseph A
Fairhurst, Shirley A
Webster, Lee R
Pickett, Christopher J
[FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**
title [FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**
title_full [FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**
title_fullStr [FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**
title_full_unstemmed [FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**
title_short [FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**
title_sort [fefe] hydrogenase: protonation of {2fe3s} systems and formation of super-reduced hydride states**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497599/
https://www.ncbi.nlm.nih.gov/pubmed/25079249
http://dx.doi.org/10.1002/anie.201406210
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