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[FeFe] Hydrogenase: Protonation of {2Fe3S} Systems and Formation of Super-reduced Hydride States**

The synthesis and crystallographic characterization of a complex possessing a well-defined {2Fe3S(μ-H)} core gives access to a paramagnetic bridging hydride with retention of the core geometry. Chemistry of this 35-electron species within the confines of a thin-layer FTIR spectro-electrochemistry ce...

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Detalles Bibliográficos
Autores principales:	Jablonskytė, Aušra, Wright, Joseph A, Fairhurst, Shirley A, Webster, Lee R, Pickett, Christopher J
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2014
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497599/ https://www.ncbi.nlm.nih.gov/pubmed/25079249 http://dx.doi.org/10.1002/anie.201406210

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