Isomerization of Olefins Triggered by Rhodium-Catalyzed C–H Bond Activation: Control of Endocyclic β-Hydrogen Elimination**

Five-membered metallacycles are typically reluctant to undergo endocyclic β-hydrogen elimination. The rhodium-catalyzed isomerization of 4-pentenals into 3-pentenals occurs through this elementary step and cleavage of two C–H bonds, as supported by deuterium-labeling studies. The reaction proceeds w...

Descripción completa

Detalles Bibliográficos
Autores principales: Yip, Stephanie Y Y, Aïssa, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497606/
https://www.ncbi.nlm.nih.gov/pubmed/25907465
http://dx.doi.org/10.1002/anie.201500596

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4497606/
https://www.ncbi.nlm.nih.gov/pubmed/25907465
http://dx.doi.org/10.1002/anie.201500596

Ejemplares similares