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Unexpected in-situ Free Radical Generation and Catalysis to Ag/Polymer Nanocomposite
In this study, we discover unexpectedly that simple reaction of AgNO(3) with oleic acid (OA) without solvent and surfactant could generate alkyl free radical which can catalyze double-bond polymerization of OA to form 1D polymeric oleic acid (POA) chain. In certain conditions, these POA chains circu...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4498183/ https://www.ncbi.nlm.nih.gov/pubmed/26160118 http://dx.doi.org/10.1038/srep11993 |